Reactions Of Substituted | Quinones
Substituted quinones are some of the most versatile electrophiles in organic chemistry. Because the quinone core is electron-deficient, their reactivity is largely governed by the nature and position of the substituents ( -groups) attached to the ring. 1. Nucleophilic Conjugate Addition (Michael Addition)
If the quinone is unsymmetrically substituted, the nucleophile typically attacks the less hindered carbon or the carbon with the lowest electron density. reactions of substituted quinones
Under UV light, substituted quinones can undergo [2+2] cycloadditions or abstract hydrogen atoms from solvents. This is frequently used in polymer chemistry and the study of DNA damage. Substituted quinones are some of the most versatile